D5229/D5229M Standard Test Method for Moisture Absorption Properties and Equilibrium Conditioning of Polymer Matrix Composite Materials has been revised to D5229/D5229M-20
Significance and Use
5.1 Procedure A is designed to produce moisture diffusion material property data that may be used as follows:
5.1.1 To determine approximate exposure times for coupon conditioning in Procedures B-E, Y, and Z;
5.1.2 As input to moisture prediction analysis computer codes; or
5.1.3 For making qualitative decisions on material selection or performance under environmental exposure to various forms of moisture.
5.2 Procedures B-E are designed to condition test coupons to a specified environmental condition or equilibrium state prior to other material property testing (including, but not limited to, mechanical testing).
5.3 Procedures Y-Z are designed to determine the loss of moisture content due to removal of a test coupon from the conditioning chamber (such as for strain gauge bonding) or due to heating of the test coupon prior to and during mechanical loading.
5.4 A single pair of tests on thin and thick specimens using Procedure A provides the moisture diffusivity constant, Dz, and the moisture equilibrium content, Mm, at the given moisture exposure level and temperature. Multiple tests at differing temperatures are required to establish the dependence of Dz on temperature. Multiple tests at differing moisture exposure levels are required to establish the dependence of Mm on moisture exposure level.
Note 1: For many polymer matrix composites, the moisture diffusivity is usually only weakly related to relative humidity and is often assumed to be a function only of temperature, usually following an Arrhenius-type exponential relation with inverse absolute temperature. For many of these materials, moisture equilibrium content is only weakly related to temperature and is usually assumed to be a function only of relative humidity (1).
5.5 Vapor-exposure testing shall be used to condition the specimen when the in-service environmental condition is a vapor such as humid air. Immersion in a liquid bath should be used to simulate vapor exposure only when apparent absorption properties are desired for qualitative purposes. Properties determined in the latter manner shall be reported as apparent properties.
Note 2: For many polymer matrix composites, the moisture absorption properties under atmospheric humid conditions are generally not equivalent to exposure either to liquid immersion or to pressurized steam. These latter environments may have different material diffusion characteristics.
1.1 This test method covers a procedure for the determination of moisture absorption or desorption properties in the through-the-thickness direction for single-phase Fickian solid materials in flat or curved panel form. Also covered are procedures for conditioning test coupons prior to use in other test methods; either to an essentially moisture-free state, to equilibrium in a standard laboratory atmosphere environment, or to equilibrium in a non-laboratory environment. Also included are procedures for determining the moisture loss during elevated temperature testing, as well as moisture loss resulting from thermal exposure after removal from the conditioning environment, such as during strain gauge bonding. While intended primarily for laminated polymer matrix composite materials, these procedures are also applicable to other materials that satisfy the assumptions of 1.2.
1.2 The calculation of the through-the-thickness moisture diffusivity constant in Procedure A assumes a single-phase Fickian material with constant moisture absorption properties through the thickness of the specimen. The validity of the equations used in Procedure A for evaluating the moisture diffusivity constant in a material of previously unknown moisture absorption behavior is uncertain prior to the test, as the test results themselves determine if the material follows the single-phase Fickian diffusion model. A reinforced polymer matrix composite material tested below its glass-transition temperature typically meets this requirement, although two-phase matrices such as toughened epoxies may require a multi-phase moisture absorption model. While the test procedures themselves may be used for multi-phase materials, the calculations used to determine the moisture diffusivity constant in Procedure A are applicable only to single-phase materials. Other examples of materials and test conditions that may not meet the requirements are discussed in Section 6.
1.3 The evaluation by Procedure A of the moisture equilibrium content material property does not assume, and is therefore not limited to, single-phase Fickian diffusion behavior.
1.4 The procedures used by this test method may be performed, and the resulting data reduced, by suitable automatic equipment.
1.5 This test method is consistent with the recommendations of CMH-17 Rev G (1),2 which describes the desirable attributes of a conditioning and moisture property determination procedure.
1.6 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.
1.6.1 Within the text, the inch-pound units are shown in brackets.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D570 Test Method for Water Absorption of Plastics
D618 Practice for Conditioning Plastics for Testing
D792 Test Methods for Density and Specific Gravity (Relative Density) of Plastics by Displacement
D883 Terminology Relating to Plastics
D2344/D2344M Test Method for Short-Beam Strength of Polymer Matrix Composite Materials and Their Laminates
D2584 Test Method for Ignition Loss of Cured Reinforced Resins
D2734 Test Methods for Void Content of Reinforced Plastics
D3171 Test Methods for Constituent Content of Composite Materials
D3878 Terminology for Composite Materials
E691Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
Military StandardMIL-B-131 Barrier Materials, Water Vapor-Proof, Grease-Proof, Flexible, Heat-Sealable Available from Standardization Documents Order Desk, DODSSP, Bldg. 4, Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098, http://dodssp.daps.dla.mil.